Method for producing a subminiature “micro-chip” oxygen sensor for control of internal combustion engines or other combustion processes, oxygen sensor and an exhaust safety switch

ABSTRACT

A method of making a sub-miniature “micro-chip” oxygen sensor is provided where multiple sensor elements are applied to a dielectric ceramic substrate consisting of a heater pattern, followed by a dielectric layer. Intermeshing electrodes are then applied either over the heater pattern/dielectric layers or on the opposite side of the substrate. The space between the intermeshing electrodes is filled with an n-type or p-type high temperature semiconductor which is covered by a porous protection layer. After singulation (dicing), the sensor element is assembled having conductors applied to the contact pads on the element and is packaged in an assembly for introduction to the exhaust stream of a combustion process. A large step-wise change in the resistance of the element takes place as a result of changes in oxygen content in the exhaust whereby one can determine if the exhaust is rich or lean for use in an engine management or combustion management systems for emissions control. A circuit is proposed to convert the change in resistance to a voltage signal to be used for control algorithms in engine or combustion control. Utilizing multiple units of the device for individual cylinder control of multi-cylinder engines is described. A method of using one embodiment of the invention for use as a safety switch is also revealed.

CROSS REFERENCE TO RELATED APPLICATIONS

This application is related to and claims priority to U.S. Provisional Application Ser. No. 61/299,487, filed Jan. 29, 2010, the disclosure of which is specifically incorporated by reference herein.

FIELD OF THE INVENTION

The present invention relates to oxygen sensors for sensing exhaust gases in an internal combustion engine or in any combustion process where control of the air-fuel ratio is desired. Of particular usefulness is the use of the sensors for control of small spark ignition engines such as those used in motorcycles, ATVs, recreational marine applications and unmanned air vehicles. In addition, the sensor is also suitable for individual cylinder control in multi-cylinder engines and hybrid engines for automotive and off-road applications. This invention may also be used as a safety device to trigger an alarm and/or disable combustion processes that produce rich exhaust gasses in enclosed spaces to prevent adverse conditions such as CO poisoning.

BACKGROUND OF THE INVENTION

The utilization of closed loop control of internal combustion engines for reducing emissions and enhancing performance has gone through an evolutionary process since the 1970's with the replacement of carburetor based systems with single port (monotronic) fuel injection controlled by utilizing the signal from an unheated oxygen sensor to determine the engine's air/fuel ratio. This has evolved into multi-port fuel injection systems with heated oxygen sensors. Currently, such technology from the automotive industry is being applied to improve emission control in small engines for motorcycle and off-road applications. However, these sensors in their present state are cost prohibitive for a vast majority of global applications.

Two major classes of oxygen sensors have been developed and have competed for the automotive market since the onset of closed-loop control. Voltaic sensors rely on voltage generation due to a chemical potential across an ion conductor (stabilized zirconia) situated between the exhaust gas and a reference gas, typically air, in accordance with the Nernst equation, which is well known to those of ordinary skill. This type of sensor undergoes a step-wise change in voltage, transitioning across stoichiometry, due to an abrupt change in oxygen concentration at that point.

A second type of sensor known as a resistive sensor relies on a step-wise change in resistance of a semiconductor material (typically titania-based) as exhaust gases transition across the stoichiometric boundary. Both classes of sensors must be heated to become functional.

Zirconia sensors have held the majority of market share, and as such have gone through the greatest evolutionary change. Initially, zirconia sensors were unheated and relied on the heat from exhaust gasses to bring them to a temperature at which they become functional. Heater elements were later added to hasten sensor activation (light-off time), and increase the numbers of possible mounting locations along the exhaust stream. Further improvements have included the use of an integrated heater with multi-layer packaging technology, i.e., a planar sensor.

More recently universal “wide-band” or “air/fuel” sensors have been developed providing the ability to determine the air-fuel ratio away from stoichiometry in a somewhat linear current vs. air-fuel relationship, as compared to the step change in voltage at stoichiometry in earlier types of sensors. Unfortunately, these sensors are very expensive, have complicated circuitry, and the size reduction potential is limited due to the need to have enough charge carriers to generate a signal. As such, they are therefore not suitable for the small engine market. By “small engine” is meant as defined by the Environmental Protection Agency, “ . . . those products rated less than or equal to 19 kilowatt (kW) (roughly equivalent to 25 horsepower [hp])” (Ref: Control of Emissions from Marine SI and Small SI Engines, Vessels, and Equipment—Final Regulatory Impact Analysis. EPA420-R-08-014, September 2008). This applies to single or multiple cylinder spark ignition or compression ignition engines, Rotary (wankel) engines, or any other mechanical device utilizing the combustion of a fuel to convert chemical energy to mechanical energy regardless of particular mechanical system employed.

Resistive sensors by their nature can be reduced in size to a much greater extent than voltaic sensors. In accordance with the invention, this characteristic is used to make a sub-miniature “micro-chip” oxygen sensor of particular usefulness in the small engine market. The invention also enables the possibility of individual cylinder control in multi-port fuel injection systems for large spark ignition engines such as automobiles. Another use is to provide a safety cut-off sensor to ensure engines are not running rich and creating noxious gases.

BRIEF SUMMARY OF THE INVENTION

In accordance with one aspect of the invention, the sensor is made with a thin, typically, about 0.005″ to about 0.015″ in thickness, fully fired or partially (bisque) fired ceramic substrate or wafer made up primarily of aluminum oxide typically, i.e., about 94% to about 99.5% by weight, or other suitable dielectric material upon which multiple thin heater patterns for mass production of multiple sensor elements may be applied. Examples of other suitable dielectric materials include but are not limited to boron nitride, steatite (magnesium silicate), zirconium toughened alumina (ZTA), etc These heater patterns are typically made of platinum, palladium, a combination thereof, or other suitable conductive material having an appropriate resistivity for the specific application.

The heater patterns may be fired to a high enough temperature, if necessary, to ensure adhesion and/or to achieve a suitable resistance value depending on the application technique employed. This firing may be delayed until later in the process. Typically, temperatures of about 650° C. to about 1400° C. constitute a high enough temperature. One or more dielectric layers is/are placed over this heater pattern to encapsulate and/or provide electrical isolation from the sensing portion of the sensor element to be applied in subsequent operations. This dielectric layer may also be fired to a suitable temperature to ensure adhesion and dielectric properties, if necessary, depending on the application technique employed. Typically, temperatures of about 650° C. to about 1400° C. constitute a high enough temperature.

Adjacent to this dielectric layer (either on top of or on the opposite side of the substrate) are placed two intermeshing “comb-shaped” electrodes of platinum, palladium, a combination thereof, or other suitable conductive material. Firing to a suitable temperature may be necessary depending on the application technique. An n or p type semiconducting material such as but not limited to TiO₂ or Cr₂O₃ based materials or other appropriate material is then applied to the electrodes in such a way as to cover and bridge a gap in the spaces between the intermeshing combs of the comb-shaped electrodes, followed by firing to a temperature and an amount of time necessary to sinter and achieve desired functional characteristics of the sensor. These functional characteristics include resistance under rich conditions, resistance under lean conditions, switch times going from rich to lean and lean to rich conditions, resistance to chemical poisoning, and the aging behavior or stability of the sensor (changes in these characteristics during the sensor's useful lifetime).

A porous protective dielectric layer may then be applied and fired to a suitable temperature sufficient to promote sintering and adhesion. By “porous” is meant sufficiently porous to allow the gases to readily pan through to the semiconducting material while preventing abrasion and poisoning. This protective layer may possess precious metal catalytic materials such as platinum, and/or palladium, and/or rhodium, as well as oxygen storage components such as cerium oxide or other suitable material as may be necessary to achieve the desired functional characteristics of the sensor. These catalytic materials may be part of the composition of the protective layer, or added as to impregnate the protective layer in a subsequent operation by applying a solvent containing dissolved or colloidal catalytic materials such as platinum, palladium, rhodium or any other suitable impregnant. At the end of these processes there results a wafer or substrate containing multiple oxygen sensor elements (chips), which are then singulated, i.e., divided out as single sensors via dicing, laser cutting, or other suitable techniques common to the semiconductor or electronics industry.

Each singulated chip element is then placed into an assembly, which is secured onto an exhaust system in such a way as to expose the sensing portion of the chip to exhaust gases. A voltage is applied to a heater circuit on the chip to bring the element to a temperature sufficient to activate the sensor. The resistance of the semiconducting portion of the element decreases with increased temperature, and either increases as it is exposed to higher levels of oxygen or decreases with increased oxygen, depending on the semiconducting material employed. By maintaining the element at an elevated temperature (above about 600° C.) the temperature effect is minimized and the condition of the exhaust gas can be determined by the step change in resistance at stoichiometry.

Four high temperature conductors are attached to the contact pads on the sensor element leading to wire connections that are connected to an electronic control unit (ECU) of the engine of the type which is conventional and of the type well known to those of ordinary skill in the art. The two wires from the heater circuit are used to apply a suitable voltage across the heater with one wire grounded (polarity does not matter) in order to heat the sensor to become active. Two wires from the sensor circuit of the chip element are connected to a circuit in the ECU. In one embodiment the step-wise resistance change can be measured directly by the ECU. In another, two resistors in a voltage divider circuit are used to enable the resistance changes in the sensor to be converted to a voltage signal between about 1 volt (rich) and about 0 volts (lean). This configuration enables matching the signal characteristics of conventional zirconia switching sensors. In reality, the signal is targeted to be slightly less than 1 volt and slightly greater than 0 volts, typically on the order of about 0.900V to 0.750V in rich condition_to about −0.050V to 0.050V in the lean condition. With this measurement system configuration there is provided interchangeability between control algorithms for this sensor and conventional zirconia switching sensors.

These and other advantages and features that characterize the invention are set forth in the claims annexed hereto and forming a further part hereof. However, for a better understanding of the invention, and of the advantages and objectives attained through its use, reference should be made to the Drawings, and to the accompanying descriptive matter, in which there are described exemplary embodiments of the invention.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic view of a ceramic substrate or wafer having multiple elements applied in a pattern suitable for singulation, i.e., separate out single elements.

FIG. 2 is a schematic side view and perspective view of a potential heater pattern having a predetermined thickness to be applied as a first layer to the substrate of FIG. 1.

FIG. 3 is a schematic side view and perspective view of one or more dielectric layer(s) to be applied over the heater pattern of FIG. 2 as a second layer on the wafer in FIG. 1, also having a predetermined thickness.

FIG. 4 is a schematic view of configuration for a potential electrode is a “comb” pattern, which is the third layer of the wafer of FIG. 1, to be applied over the dielectric layer of FIG. 3 at a 90 degree orientation to the heater pattern of FIG. 2, or applied to the substrate on the opposite side of the heater pattern.

FIG. 5 is a schematic side view and perspective view of semiconducting material of predetermined thickness to be applied in a pattern over the electrodes of FIG. 4 in such a way as to bridge a gap between the combs, with the semiconductor pattern being the fourth layer on the wafer of FIG. 1.

FIG. 6 is a schematic side view and perspective view of the porous dielectric protective layer to be applied over the semiconducting layer of FIG. 5, and is the fifth layer on the wafer of FIG. 1.

FIG. 7 is a schematic view and an exploded perspective view of individual element assembly containing the elements illustrated in FIG. 2 through FIG. 6 and, having the heater and the sensor circuits on the opposite sides of the element substrate (chip).

FIG. 8 is a schematic side view and an exploded perspective view of a second individual element assembly containing the elements illustrated in FIG. 2 through 6, having the heater and sensor circuits on the same side of the element substrate (chip).

FIG. 9 is a schematic view of an inner ceramic insulator upon which the element assembly with attached conductors of FIG. 10 is placed.

FIG. 10 is a schematic view of conductor terminals used to connect the sensor element and heater circuits of FIG. 7 a or 7 b to wires leading to the electronic engine/combustion control system.

FIG. 11 is a schematic end view and side view (in cross-section) of the element assembly of FIG. 9, positioned on the end of the inner ceramic insulator of FIG. 8, and having conductors terminals of FIG. 10 attached to contact pads on the element having heater and sensor circuit on opposite sides of the element substrate (chip).

FIG. 12 is a schematic view of the element assembly of FIG. 7 or 8, positioned on the end of the inner ceramic insulator of FIG. 9, and having conductor terminals of FIG. 10 attached to contact pads on the element having heater and sensor circuit on the same side of the element substrate (chip).

FIG. 13 is a schematic view of a two-piece outer ceramic insulator which is placed over the sub-assembly of FIG. 8.

FIG. 14 is a schematic view of the sub assembly containing the element/conductor sub assembly of FIG. 10 along with the insulators of FIG. 9 and FIGS. 11 and 12.

FIG. 15 is a schematic view of a threaded metal housing.

FIG. 16 is a schematic view of an insulating disk having passages through which conductors may pass.

FIG. 17 is a schematic side cross-section view of the sensor assembly.

FIG. 18 is a schematic view of a sensor electrical connection including a voltage divider circuit, which may be placed in a connector housing or in an electronic control unit, is used for sensing oxygen in exhaust gases.

FIG. 19 is a schematic view of the use of the invention in a one-cylinder engine application.

FIG. 20 is a schematic view of the current industry's use of oxygen sensors in multi-cylinder engine applications.

FIG. 21 is a schematic view of the use of the invention in multi-cylinder engine applications for individual cylinder control.

DETAILED DESCRIPTION OF THE INVENTION

As shown in FIG. 1, for purposes of illustration only and not limitation, the present invention includes a thin, typically about 0.005″ to about 0.015″ thick ceramic substrate or wafer 11 made primarily of aluminum oxide in a ratio of about 94% to about 99.5% by weight, or other suitable dielectric material upon which multiple elements may be produced by first applying thin heater patterns composed of platinum, palladium, a combination thereof, and/or other suitable materials, and placed thereon. Such suitable dielectrics include but are not limited to boron nitride, steatite (magnesium silicate), zirconium toughened alumina (ZTA), etc. . . . .

The heater patterns, as shown in FIG. 2, can be applied using physical vapor deposition (electron beam or sputtering) or electroless plating, then masking using photolithography techniques followed by chemical etching. Alternatively, the heater pattern 15 can be applied by first masking the substrate using photolithography techniques, then applying the platinum, palladium, or other suitable heater material using the techniques described above and removing the mask to leave the heater patterns on the substrate. Typical thicknesses of this metal layer making up the heater are between 25 and 1250 nm as needed to achieve desired resistance values. It is also understood by those familiar with the art, that often a thin (5 to 15 nm thick) coating of titanium, vanadium or other suitable material may be applied between the metal (Pt, Pd, etc. . . . ) and adjacent layers (substrate, cover layers, etc.) to improve adhesion. An example of a heater pattern 15 is illustrated in FIG. 2, but it need not be limited to such configuration. In one embodiment, it may be suitable to fire the heater pattern to elevated temperatures of between about 650° C. and about 1450° C. and hold for 0.25 to 6 hrs at some point in the manufacturing process to improve adhesion and/or achieve desired electrical resistivity as a result of sintering.

Following the application of the heater patterns 15, an electrically insulating layer 17 as shown in FIG. 3, and composed primarily of Al₂O₃ or other suitable dielectric material is applied via screen printing, using Direct-Write Technology (DWT), ink-jet printing, or using photolithography masking and vapor deposition techniques or vapor deposition and etching techniques. Direct-Write Technology involves dispensing a liquid or a paste material (in this case dielectric in an organic carrier) through a needle or other small orifice with the aid of a computer controlled positioning and dispensing unit with deposition control in three axes. Following the application of the insulating dielectric layer 17, firing to an elevated temperature between about 650° C. and about 1400° C. is performed as necessary to sinter and/or improve adhesion.

The comb shaped electrodes 19 shown in FIG. 4 are preferably made of platinum, palladium, a combination thereof and/or other suitable conductor material. The electrodes are applied with the contact pads at 90 degrees from the heater contact pads on either the same side of the substrate as the heater pattern, or on the opposite side. These electrode patterns 19 are applied using photolithography masking and either vapor deposition or electroless plating as is suitable. Following application, photo resist is removed and the electrodes are fired at an elevated temperature of between about 650° C. and about 1400° C. and hold for 0.25 to 6 hrs to improve adhesion and adjust electrode conductivity.

An n or p type semiconductor bearing material such as TiO₂ or Cr₂O₃ as shown in FIG. 5 is applied to the electrode 21 to a suitable thickness typically between 5 and 150 microns to cover and bridge the gap between the combs of the electrode 19. The material may be applied as a paste using screen printing, ink-jet printing, or Direct Write Technology as is appropriate. Following application, the wafer is dried to a temperature of approximately 90 to 125° C. for 0.5 to 6 hrs and fired to an elevated temperature between about 650° C. and about 1300° C. and hold for 0.25 to 6 hrs to remove organic carrier materials, sinter, and improve adhesion. Alternatively, this layer may also be applied using photolithography masking and vapor deposition techniques.

A porous dielectric paste material 23 as shown in FIG. 6 which is composed of organic carriers common in the printing industry, with solids such as Aluminum Oxide based compositions, or spinel (magnesium aluminate) is applied over the semiconducting material using, screen printing, ink-jet printing, or Direct Printing Technology to a thickness of between about 5 and about 150 microns. Following the application of this material it is dried at temperatures of approximately 90 to 125 deg C. for 0.5 to 6 hrs, then fired to a temperature between about 650° C. and about 1100° C. and held for 0.25 to 6 hrs. This material may possess catalytic materials such as platinum, and/or palladium, and/or rhodium, and/or an oxygen storage component such as Ce₂O₃ in concentrations suitable to achieve the desired functional behavior of the sensor. Alternatively, these catalytic materials may be applied after firing using an impregnant applied manually or robotically using a syringe or applied using Direct Printing Technology.

FIGS. 7 and 8 are schematic views of two versions of complete sensor elements 25 and 27 with all layers illustrated. As may be appreciated from the foregoing discussion, the main components of the sensor have been discussed and illustrated. However, as will be readily apparent to those of ordinary skill, for the platinum layer it may be desirable to add a thin layer, typically about 5 to about 15 nanometers, of titanium (optional) or vanadium or other pure suitable material to both sides of each platinum layer to promote adhesion to the aluminum oxide layer. Thus, a typical sequential arrangement of layers is as follows:

Version 1 Version 2 (FIG. 7) (FIG. 8) 1. Aluminum oxide substrate (11); 2. Titanium; Side A Side A 3. Platinum heater (15); Side A Side A 4. Titanium; Side A Side A 5. Dielectric (17); Side A Side A 6. Titanium; Side B Side A 7. Platinum electrode (19); Side B Side A 8. Titanium; Side B Side A 9. Semiconductor (21) Side B Side A 10. Porous Cover layer (23). Side B Side A

The sensor assembly 29 is now described. As shown in FIG. 9, on the tip of the inner ceramic part, there is a recess whose length and width is slightly larger than the element chip, and whose depth is slightly smaller than the chip to allow for positioning and securing the chip in the assembly and allowing for typical dimensional tolerances found in production. There is also a gap along the centerline of the inner ceramic to avoid contact of the center portion of the chip to promote thermal isolation immediately adjacent to the heated portion in the center of the chip. The element chip of FIG. 7 is positioned on the center of the end of the inner ceramic in the recess. Current carrying conductors or terminals 39 of FIG. 10 made of materials suitable for the operating environment, i.e., the temperature and exhaust gas atmosphere (ex.: Inconel 600, Inconel 625, etc. . . . ), are then attached to the four contact pads of the chip and commuted through the grooves in the outer edges of the inner ceramic as shown in FIGS. 11 and 12. FIG. 11 also shows a sensor side 49 and heater side 51. Securing terminals to the contact pads for improved electrical contact may be achieved using a high temperature conductive paste (Pt, Pd, etc.), high temperature brazing, laser welding, or may simply be done by providing a mechanical contact assembly. This sub assembly is then inserted into a two-piece outer insulator of FIG. 13, which has a hole for exhaust gases to reach the sensing portion of the chip as shown in FIG. 14

This outer ceramic insulator 101, 103 of FIG. 13 also provides mechanical security and electrical insulation for the conductive terminals. There are two outer diameters on the first outer ceramic part 101 which will be used to seat the ceramic sub-assembly in a metal housing of FIG. 15. The second outer ceramic 103 is a bushing having the same inner diameter, and the larger outer diameter of the first part. The sensor element 13, an inner insulator 107, heater terminals 105, signal terminals 109, and inner insulator 111 are also shown. This metal housing or “shell” shown in FIG. 15 has an internal transition feature, which mates to the outer ceramic part and has a suitable standard thread and hexagonal faces of suitable size for installation into an exhaust pipe. The ceramic sub-assembly is placed into the shell, small amounts of high temperature potting material are placed around each conductor, and a thin round ceramic wafer or disk of FIG. 16 having holes of appropriate geometry is then placed over the conductors and pushed into place against the end of the two concentric ceramic parts. The back end of the shell is then crimped to secure all components of the assembly as shown in FIG. 17. This assembly shows an outer shell 203 and cement seal 201. This assembly may require further heat treatment as may be necessary to cure the potting material used for sealing.

The circuitry of the invention may be used for a number of applications. The oxygen sensor may be used for engine control. In one illustrative embodiment, FIG. 18 illustrates a sensor along with a voltage divider circuit that may or may not be employed depending upon the particular application. This voltage divider circuit can be physically located either in an electronic control unit or in a harness connector as may be appropriate for the application. It may also be incorporated in the sensor assembly or on the sensor element itself; however, this may not be practical due to the high temperatures reached in the sensor may adversely influence the resistance values of the voltage divider over time. The material chosen for the element sensor resistor (R_(s)) is chosen to be an n-type material which increases in resistance with increasing oxygen in exhaust gases. A voltage, V, typically between about 5V and about 18V is applied to the heater circuit (R_(h)) to heat the sensor element resistor (R_(s)) to a temperature at which the sensor becomes active, such that the sensor circuit resistance responds to changes in the level of oxygen in the exhaust gas. That same voltage may be applied to voltage divider circuit (R₁/R_(s)/R₂), or a separate and different voltage may be applied. Signal stability and therefore, performance is improved by regulating the voltage applied to this circuit to a stable level. The ratio of R₂ to R₁ is chosen based upon the applied voltage, and is typically the same as or near the applied voltage (e.g., 12:1 for 12 volts, 14:1 for 14 volts, etc. . . . ). The value chosen for R₂ (and therefore R₁ also) is dependent upon the system such that the voltage measured in the lean condition stays below the target value, typically <100 mV, for the particular system. Both of these values are dependent upon the resistive characteristics of the element under the operating conditions, therefore the location of the sensor in the exhaust stream may have an impact on the resistance values chosen.

FIG. 19 illustrates a use of the device of the invention for engine control for a one (1) cylinder engine, for example, for a motorcycle. FIG. 20 illustrates engine control in a multi-cylinder environment according to the prior art where one oxygen sensor controls four (4) cylinders using an averaging effect. FIG. 21 illustrates a use of the device of the invention wherein one (1) oxygen sensor is provided per cylinder in a multi-cylinder engine providing individual cylinder control.

The device may also be used as a safety switch. More specifically, in another embodiment, the invention may be used as a safety switch for engines designed to run lean in an enclosed environment to prevent the generation of toxic gases such as CO. By selecting a p-type semiconducting material, e.g., Cr₂O₃, instead of an n-type material, e.g., TiO₂, the resistance is low in lean exhaust environments and high in rich exhaust gas environments. For instance, many propane powered devices (floor buffers, burnishers, Zamboni™, etc. . . . ) require a sensor to detect when the engine begins to run rich creating, carbon monoxide and other noxious gases this sensor would be used to sense the condition triggering an engine shut-down and/or an alarm. Some companies use oxygen sensors for this purpose; however, they are not well suited for these applications as they are too large and expensive. A voltage divider circuit may or may not be employed depending on the particular application.

The ability to produce these sensors in very small sizes (micro-chip size) with significant reduction in cost of production along with the greatly reduced power requirements as compared to conventional oxygen sensors used in the automotive industry makes this technology ideally suited for the motorcycle and small engine markets. Additionally, these same features provide an opportunity for utilizing one sensor per cylinder on multi-cylinder applications, e.g., automobiles and compressed natural gas power generators, for individual cylinder control emission strategies.

While the present invention has been illustrated by a description of various embodiments and while these embodiments have been described in considerable detail, it is not the intention of the Applicant to restrict, or any way limit the scope of the appended claims to such detail. The invention in its broader aspects is therefore not limited to the specific details, representative apparatus and method, an illustrative example shown and described. Accordingly, departures may be made from such details without departing from the spirit or scope of Applicant's general inventive concept. 

What is claimed is:
 1. A method of making an oxygen sensor, comprising: depositing on a dielectric substrate multiple resistive heater circuits; depositing second dielectric layers on the resistive heater circuits; depositing conductive intermeshing comb electrodes on the dielectric layer or on the substrate on the opposite side of the heater pattern; applying one of n-type or p-type high temperature semiconductors on the comb electrodes bridging the gap between the legs of the combs; applying porous dielectric protective layers containing catalytic precious metals on the semiconductors; and isolating individual elements via a singulation process to produce multiple individual oxygen or gas sensor elements.
 2. The method of claim 1, wherein a heater pattern is placed on a ceramic substrate with the sensing element on the same side of the substrate as the heater having a dielectric barrier printed or otherwise deposited between the two.
 3. The method of claim 1, wherein physical vapor deposition is used to deposit conductive materials for heater patterns and/or electrodes on the sub-miniature oxygen or gas sensors.
 4. The method of claim 1, wherein electroless plating is used to deposit conductive materials for heater patterns and/or electrodes on the sub-miniature oxygen or gas sensors.
 5. The method of claim 1, wherein physical vapor deposition is used to deposit dielectric materials to electrically insulate the heater circuit from the sensor circuit of the oxygen sensor.
 6. The method of claim 1, wherein Direct-Write Technology is used to deposit the dielectric, semiconducting, or porous cover layer materials to the oxygen sensor elements.
 7. The method of claim 1, wherein ink-jet printing is used to deposit the dielectric, semiconducting, or porous cover layer materials to the oxygen sensor elements.
 8. An oxygen sensor for sensing exhaust gases from a combustion process, comprising: a fired ceramic dielectric substrate; at least one heater circuit adhered to a surface of the substrate, with at least one dielectric layer encapsulating the heater circuit to provide electrical isolation; at least one electrode adhered on the substrate apart from the dielectric layer encapsulated pattern of heater circuit; an n-type or p-type semiconducting material on the electrode and adjacent the electrode.
 9. The sensor of claim 8, wherein the semiconducting material is composed of a n-type high temperature semiconductor.
 10. The sensor of claim 8, wherein the semiconducting material is composed of a p-type high temperature semiconductor.
 11. The sensor of claim 8, further comprising a porous protective dielectric layer applied to the electrode over the semiconducting layer.
 12. The sensor of claim 8, further comprising a housing assembly for holding the sensor in a manner exposed to exhaust gases from a combustion process.
 13. The sensor of claim 12, further comprising wires connected to the heater circuit and to at least one electrode for heating the sensor and detecting a resistance change representative of sensed exhaust gases.
 14. The sensor of claim 8, wherein said substrate is made of aluminum oxide and the electrode is made of platinum, palladium, or a combination thereof.
 15. The sensor of claim 8: wherein the at least one electrode comprises a conductive intermeshing comb electrode disposed on the dielectric layer or on the substrate on a side opposite of the heater pattern; a porous dielectric protective layer disposed such that the at least one electrode is disposed between the porous dielectric protective layer and the substrate, wherein the porous dielectric protective layer contains catalytic precious metals. 